Russian Chemical Bulletin p. 647 - 650 (1995)
Update date:2022-08-11
Topics:
Skakovskii, E. D.
Rykov, S. V.
Tychinskaya, L. Yu
Murashko, V. L.
Ogorodnikova, M. M.
et al.
Photolysis of solutions of benzyl acetate in CD3OD has been studied.As has been established based on the effects of CIDNP and the yields of products, decomposition of the starting compound occurs from both excited singlet and triplet electronic states.The contributions of homolysis and solvolysis to the overall photochemical process have been measured, and the lifetimes of the acetoxy radicals formed have been evaluated.Toluene-d has been shown to be formed mostly by disproportionation of benzyl radicals with hydroxymethyl radicals derived from the solvent molecules.Key words: benzyl acetate; methanol; photolysis; homolysis; solvolysis; CIDNP effects.
View More
Wuxi Pharma-Trading Import & Export Co.,Ltd.
Contact:+86-510-82304590 82716390
Address:Room 523,Youzu Alliance Building,No.88 Renmin Zhonglu,Wuxi,Jiangsu,China
Nanjing Samwon International Limited
Contact:+86-25-84873444
Address:1108, BLDG B, New Century Plaza, No 1, South Taiping Rd.,
Contact:+49-4101-3053-0
Address:Waldhofstrasse 14 ,25474 Ellerbek Germany
HANGZHOU EVC CHEMICAL CO.,LTD.(expird)
Contact:+86-571-88296056
Address:Room#3001,Zhejiang Chemical Market,No.10,Road Shenban,Hangzhou,Zhejiang,China
Ji'nan Orgachem Pharmaceutical Co.,Ltd
Contact:+86-531-82687810
Address:Jinan
Doi:10.1002/pro.284
(2010)Doi:10.1002/chem.200800283
(2008)Doi:10.1002/chem.201203923
(2013)Doi:10.1039/c0cp00565g
(2010)Doi:10.1039/c7dt04850e
(2018)Doi:10.1016/0031-9422(88)80280-2
(1988)
