Mild and fast deoxygenation of aromatic carbonyl compounds by dimethylamine borane/titanium tetrachloride

Article abstract of DOI:10.1080/00397919608003512

The title reaction proceeds in dichloromethane at room temperature within 1/2 hour. Benzylic alcohols are intermediates. TiCl₄ can be replaced by other (although less effective) Lewis acids such as AlCl₃, BF₃·ether, FeCl₃.

Full text of DOI:10.1080/00397919608003512

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Synthetic Communications: An
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Mild and Fast Deoxygenation of
Aromatic Carbonyl Compounds
by Dimethylamine Borane /
Titanium Tetrachloride
a
a
Eckehard V. Dehmlow , Thomas Niemann & Anke
a
Kraft
a
Fakultät für Chemie, Universität Bielefeld
Postfach , 100131, D-33501, Bielefeld, Germany
Published online: 15 Aug 2006.
To cite this article: Eckehard V. Dehmlow , Thomas Niemann & Anke Kraft (1996)
Mild and Fast Deoxygenation of Aromatic Carbonyl Compounds by Dimethylamine
Borane / Titanium Tetrachloride, Synthetic Communications: An International Journal
for Rapid Communication of Synthetic Organic Chemistry, 26:8, 1467-1472, DOI:
10.1080/00397919608003512
To link to this article: http://dx.doi.org/10.1080/00397919608003512
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