POLYMERꢀMODIFIED SUPPORTED PALLADIUM CATALYSTS
367
Table 4. Results of the hydrogenation of ꢀhexꢀ2ꢀyne (2.23 mmol) on palladium catalysts (0.01 g) in ethanol (25 mL) at
n
40
°
C and 0.1 MPa
Maximum rate
of reaction
cisꢀ2ꢀHexene selectiviꢀ
Catalysts
Conversion, %
Stability (TON)
ty, %
–6
(
Wmax
×
10 , mol/s)
1
1
1
%Pd/ZnO
6.2
7.0
7.8
86.1
90.5
89.5
98.8
97.2
99.5
9480
16590
33180
%Pd–PEG/ZnO
%Pd–BP/ZnO
from ethylene, propylene, etc., which inhibit their catꢀ
alytic polymerization).
8. Ivanchev, S.S. and Dmitrenko, A.V., in Kompleksnye
metalloorganicheskie katalizatory polimerizatsii olefinov
(Organometallic Complex Catalysts for Olefin Polymerꢀ
ization), vol. X: Sintez i svoistva polimerizatsionnoꢀnapolꢀ
nennykh poliolefinov (Synthesis and Properties of Polyꢀ
merizationꢀFilled Polyolefins), D’yachkovskii, F.S., Ed.,
Chernogolovka, Moscow oblast: Inst. Khimicheskoi
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. Kritskaya, D.A. and Ponomarev, A.N., Vysokomol. Soeꢀ
din., Ser. B: Khim. Polim., 1975, vol. 17, p. 67.
0. Tal’roze, R.V., Shandryuk, G.A., Merekalov, A.S.,
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ACKNOWLEDGMENTS
We are grateful to Senior Researcher S.G. Protaꢀ
sova and Leading Researcher A.M. Ionov (Institute of
Solid State Physics, Russian Academy of Sciences,
Chernogolovka) for performing XPS analysis. This
work was supported by the Committee of Science of
the Ministry of Education and Science of the Republic
of Kazakhstan and, in part, by the Russian Foundation
for Basic Research (project no. 14ꢀ03ꢀ00675).
9
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Translated by V. Makhlyarchuk
KINETICS AND CATALYSIS Vol. 57
No. 3 2016