Reductive Dimerization of Carbonyl Compounds using Reduced and Electroreduced Tungsten Species

DOI: 10.1039/c39840000341

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 341 - 342 (1984)

Update date:2022-08-11

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Authors:

Petit, Michele

Mortreux, Andre

Petit, Francis

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Article abstract of DOI:10.1039/c39840000341

Carbonyl compounds are easily transformed into olefins by chemically or electrochemically reduced tungsten species; the best results are obtained by means of a controlled potential electroreduction of WCl6 at a platinum electrode: benzaldehyde gives stilbene quantitatively when anhydrous tetrahydrofuran is used as the solvent and aluminium as the anode; in CH2Cl2, styrene can also be produced with lower yields.

Full text of DOI:10.1039/c39840000341

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