Journal of the Chemical Society. Chemical communications p. 1234 - 1235 (1985)
Update date:2022-08-17
Topics:
Gevorgyan, Vladimir
Lukevics, Edmunds
Ketones, alkyl and aryl halides, nitriles, and amides undergo reduction with lithium aluminium hydride in the solid LiAlH4-hydrocarbon two-phase system in the presence of typical phase-transfer catalysts (crown ethers and quaternary ammonium salts), The reaction being characterized by good yields; solubilization of lithium aluminium hydride in non-polar solvents is demonstrated.
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