Novel Functional Group Selectivity in Reductions with Lithium Borohydride in Mixed Solvents Containing Methanol

DOI: 10.1039/c39830000668

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 668 - 669 (1983)

Update date:2022-08-10

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Authors:

Soai, Kenso

Ookawa, Atsuhiro

Hayashi, Hiroshi

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Article abstract of DOI:10.1039/c39830000668

Primary amides were reduced selectively in the presence of carboxylic acid salts or secondary aliphatic amides by lithium borohydride in diglyme-methanol, and esters and epoxides were selectively reduced rapidly by LiBH4 in the presence of nitro, chloro, or amide groups in ether containing a small amount of methanol.

Full text of DOI:10.1039/c39830000668

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