Study of the mechanism of photochemical carbonylation of benzene catalyzed by Rh(PMe3)2(CO)Cl

DOI: 10.1021/ja00100a013

Source and publish data:

Journal of the American Chemical Society p. 9498 - 9505 (1994)

Update date:2022-08-18

Topics:

Authors:

Rosini, Glen P.

Boese, William T.

Goldman, Alan S.

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Article abstract of DOI:10.1021/ja00100a013

Although near-UV irradiation of Rh(PMe₃)₂(CO)Cl (1) has been shown to lead to efficient carbon-hydrogen bond activation, the title reaction is promoted with much greater efficiency by shorter wavelength (λ < ca. 320 nm) irradiation:

Full text of DOI:10.1021/ja00100a013

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