Tetrahedron Letters p. 1357 - 1360 (1982)
Update date:2022-08-16
Topics:
Shinkai, Seiji
Kuroda, Hideo
Manabe, Osamu
The oxidation rate of 3,5-di-t-butylsalicyl alcohol by 3-methyl-10-ethyl-5-deazaisoalloxazine was found to be very sensitive to solvent effect, the rate constant in 99 volpercent DMF being greater by a factor of 37 than that in 50:50 (v/v) DMF-water mixed solvent.The result suggests the importance of the aprotic nature of the reaction environment during the oxidation of alcohols by NAD+.
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