Journal of the Chemical Society. Chemical communications p. 1426 - 1428 (1989)
Update date:2022-08-16
Topics:
Muralidharan, S.
Beveridge, Kathryn anne
Wan, Peter
The acid catalyzed photoretro-aldol type reaction of m-nitro-substituted derivatives was found to give 3-(N-3'-nitrobenzyl-N-hydroxyamino)benzyl alcohol (4) as the only product derived from the nitrobenzyl fragment; the structure of (4) has been determined by X-ray crystallography and the mechanism for its formation requires the intermediacy of a non-Kekulee intermediate an which direct transmission of charge between the 1,3-positions of the benzene ring occurs.
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