THERMOLYSE VON (α-BROM-α-METHOXYMETHYL)SILANEN

DOI: 10.1016/0022-328X(86)80239-X

Source and publish data:

Journal of Organometallic Chemistry p. C1 - C4 (1986)

Update date:2022-08-17

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Authors:

Schubert, U.

Steib, Ch.

Weiss, K.

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Article abstract of DOI:10.1016/0022-328X(86)80239-X

When heated to 110 deg C, Ph3Si-CBr2OMe (2) decomposes quantitatively to Ph3SiBr, CO and MeBr.Formation of the intermediate bromo(methoxy)carbene is assumed.In contrast, thermolysis of Ph3Si-CHBrOMe (1) at 150 deg C, yields a mixture of products, the main component being Ph2(MeO)Si-CHBrPh (3).

Full text of DOI:10.1016/0022-328X(86)80239-X

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