Journal of Organometallic Chemistry p. C1 - C4 (1986)
Update date:2022-08-17
Topics:
Schubert, U.
Steib, Ch.
Weiss, K.
When heated to 110 deg C, Ph3Si-CBr2OMe (2) decomposes quantitatively to Ph3SiBr, CO and MeBr.Formation of the intermediate bromo(methoxy)carbene is assumed.In contrast, thermolysis of Ph3Si-CHBrOMe (1) at 150 deg C, yields a mixture of products, the main component being Ph2(MeO)Si-CHBrPh (3).
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