Journal of the Chemical Society. Chemical communications p. 539 - 540 (1995)
Update date:2022-08-23
Topics:
Fraile, Jose M.
Garcia, Jose I.
Mayoral, Jose A.
Menorval, Louis C. de
Rachdi, Ferid
Silica treated with Ti(OPri)4 is an efficient catalyst for the tert-butyl hydroperoxide epoxidation of nonfunctionalized alkenes and allylic alcohols at room temperature; the reactivity of the olefinic substrate depends on the structure, which allows the selective epoxidation of compounds containing different types of double bonds; 1H and 13C CP-MAS NMR shows the presence of isopropoxide groups in the catalyst.
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