Angewandte Chemie - International Edition p. 6096 - 6100 (2010)
Update date:2022-08-28
Topics:
Kikukawa, Yuji
Yamaguchi, Kazuya
Mizuno, Noritaka
Zinc in: Polyoxometalate 1 reacts with Zn2+ ions in acetone to form a novel sandwichtype POM 2 in almost quantitative yield. The H2O2-based oxidation of secondary alcohols with 2 efficiently proceeds, with an activity and chemoselectivity that is very different from those of tungsten-based catalysts including 1 (see scheme; green Zn).
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