Journal of Organic Chemistry p. 2622 - 2625 (1982)
Update date:2022-08-17
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Colon, Ismael
A new method for the reduction of a variety of organic halides has been developed.The reaction takes place under mild conditions and employs water, zinc, and a catalytic amount of nickel chloride, triphenylphosphine, and iodide ion.The reduction of p-chloroanisole by this method was investigated in some detail.The reaction rate was first order in nickel and aryl halide but independent of the water concentration.A brief mechanism of this reaction is presented.
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