Journal of Organometallic Chemistry p. 131 - 138 (1986)
Update date:2022-08-11
Topics:
Rollin, Yolande
Troupel, Michel
Tuck, Dennis G.
Perichon, Jacques
The electrochemical reduction of a dilute solution of NiX2bipy (bipy = 2,2'-bipyridine) in N-methylpyrrolidone gives the corresponding Ni0 complex, which undergoes oxidative addition with an excess of an organic halide RX to form RNiX.Decomposition of RNiX gives the dimer R2 in good yield and nickel(II).The nickel(0) species is regenerated to give an electrocatalytic process.The possible mechanism of these reactions is discussed briefly.
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