Photolysis of Matrix-Isolated Cyclopropylidene Ketene: Kinetic and Theoretical Studies of the Cyclopropylidene Formation

DOI: 10.1021/j100016a038

Source and publish data:

Journal of Physical Chemistry p. 5977 - 5985 (1995)

Update date:2022-08-30

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Authors:

Monnier, Maurice

Allouche, Alain

Verlaque, Patrick

Aycard, Jean-Pierre

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Article abstract of DOI:10.1021/j100016a038

Cyclopropylidene ketene 2 is generated by ultraviolet irradiation (λ >/= 230 nm) of cyclopropanecarbonyl chloride isolated in argon matrices at 15 K.FT-IR spectra of the primary photolysis products (2 and HCl) trapped in the same cage show the formation o

Full text of DOI:10.1021/j100016a038

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