Asymmetric synthesis XXII: Asymmetric catalytic trimethylsilylcyanation of benzaldehyde by novel Ti(IV)-chiral Schiff base complexes

DOI: 10.1016/0957-4166(95)00025-K

Source and publish data:

Tetrahedron Asymmetry p. 405 - 408 (1995)

Update date:2022-08-28

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Authors:

Jiang Jiang

Zhou Zhou

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Article abstract of DOI:10.1016/0957-4166(95)00025-K

Benzaldehyde has been trimethylsilylcyanated with a catalyst prepared in situ from titanium tetraisopropoxide and a novel chiral Schiff base. Both (R) and (S) cyanohydrins are obtained in moderate e.e. values.

Full text of DOI:10.1016/0957-4166(95)00025-K

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