Chemistry Letters p. 931 - 934 (1986)
Update date:2022-08-29
Topics:
Kobayashi, Yoshiyuki
Hayashi, Hiroaki
Miyaji, Koji
Inoue, Shohei
Transcyanohydrination, the reaction between an aldehyde and acetone cyanohydrin to give the cyanohydrin of the aldehyde, catalyzed by cyclo((S)-phenylalanyl-(S)-histidyl) gives the product with optical yield up to 63 percent from some aromatic and aliphatic aldehydes.The reaction catalyzed by (S)-α-dimethylamino-ε-caprolactam gives the product with optical yield of 15 - 25 percent from aliphatic aldehydes.
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