Chemistry Letters p. 217 - 220 (1984)
Update date:2022-08-16
Topics:
Mochida, Isao
Iwai, Yasuo
Fujitsu, Hiroshi
CoTPP supported on fine TiO2-120s pretreated by the evacuation at 250 deg C exhibited a remarkable activity, 2.2 mol NO/mol CO.min, for the reduction of NO with CO at 100 deg C.The pretreatment modified the structures of CoTPP to be insoluble in benzene but still soluble in quinoline.Such an activity is assumed to originate from the thermally-modified CoTPP of dimeric form with major loss of phenyl groups interacting more favorably with the properly dehydrated support.
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