Chemistry Letters p. 893 - 896 (1986)
Update date:2022-08-11
Topics:
Hashimoto, Mitsunori
Eda, Yutaka
Osanai, Yasutomo
Iwai, Toshiaki
Aoki, Seiichi
In the presence of a catalytic amount of 2-cyclohexen-1-one, decarboxylation of α-amino acids proceeds smoothly and affords the corresponding amino compounds in good yields.Optically active amino compounds, (3R)-(-)-3-hydroxypyrrolidine and (2R)-(-)-2-hydroxypropylamine are obtained in 93percent and 80percent yields, respectively.
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