Influence of Si surface structure on reaction mechanism: Atomic hydrogen + adsorbed Br

Article abstract of DOI:10.1063/1.464965

The reaction of atomic hydrogen with adsorbed Br is compared on Si(100) and Si(111) surfaces from 50 deg C to 300 deg C.On both surfaces, Br removal rate is first order in atomic hydrogen flux, first-order in Br coverage, and exhibits a near zero activation energy.On Si(111), this rate also depends on surface hydrogen coverage, indicating that different mechanisms occur on these surfaces.

Full text of DOI:10.1063/1.464965

Influence of Si surface structure on reaction mechanism: Atomic
hydrogen+adsorbed Br
D. D. Koleske and S. M. Gates
Citation: The Journal of Chemical Physics 98, 5091 (1993); doi: 10.1063/1.464965
View online: http://dx.doi.org/10.1063/1.464965
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/98/6?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
141.218.1.105 On: Mon, 22 Dec 2014 05:40:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
141.218.1.105 On: Mon, 22 Dec 2014 05:40:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
141.218.1.105 On: Mon, 22 Dec 2014 05:40:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
141.218.1.105 On: Mon, 22 Dec 2014 05:40:26

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
141.218.1.105 On: Mon, 22 Dec 2014 05:40:26