Preparation of (phenylsulfinyl)phenols from aryl phenylsulfinates: 'Thia-Fries rearrangement'

DOI: 10.1016/0040-4039(95)02068-3

Source and publish data:

Tetrahedron Letters p. 7 - 8 (1996)

Update date:2022-08-11

Topics:

Authors:

Jung, Michael E.

Lazarova, Tsvetelina I.

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Article abstract of DOI:10.1016/0040-4039(95)02068-3

Treatment of aryl phenylsulfinates 5 (prepared from phenols 1 by reaction with phenylsulfinyl chloride) with AlCl₃ at 25°C furnishes good yields of the (phenylsulfinyl)phenols 2 via a 'thia-Fries rearrangement'.

Full text of DOI:10.1016/0040-4039(95)02068-3

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