Tetrahedron p. 4408 - 4413 (2016)
Update date:2022-08-16
Topics:
Xu, Huixia
Sun, Peng
Wang, Kexiang
Miao, Yanqin
Yang, Tingting
Wang, Hua
Xu, Bingshe
Wong, Wai-Yeung
A novel host material, namely 9-(6-(3-phenyl-5-(pyridin-2-yl)-4H-1,2,4-triazol-4-yl)hexyl)-9H-carbazole (PPHCZ) was designed and synthesized by incorporating 1, 2, 4-triazol as the electron-withdrawing moiety and carbazole as electron-donating moiety using hexyl as bridge. The photophysical, electrochemical, thermal properties and performances in phosphorescent organic light-emitting devices (PhOLED) were thoroughly characterized. PPHCZ with a high triplet energy level (3.01?eV) exhibited an obvious intermolecular interaction in thin film. Green and blue PhOLEDs using fac-tris(2-phenylpyridine)iridium and iridium(III) bis(4,6-difluorophenyl)-pyridinato [Formula presented],C2′]picolinate as phosphorescent dopants have been fabricated.
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