Selective hydrogenation of simple and functionalized conjugated dienes using a binuclear palladium complex catalyst precursor

DOI: 10.1016/00404-0399(50)11207-

Source and publish data:

Tetrahedron Letters p. 5673 - 5676 (1995)

Update date:2022-08-10

Topics:

Authors:

Cho, In Sik

Alper, Howard

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Article abstract of DOI:10.1016/00404-0399(50)11207-

The selective 1,2-hydrogenation of simple and functionalized conjugated dienes is catalyzed by preactivation of the binuclear palladium complex, [(Bu(t)₂PH)PdPBu(t)₂]₂ with oxygen, in THF at room temperature and 1 atm of hydrogen pressure, to form monoenes in excellent yield.

Full text of DOI:10.1016/00404-0399(50)11207-

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