One-Pot Conversions of (Silylmethyl)cyclopropanes to Homoallylic Alcohols and 1,4-Diols Based on Haloborane-Induced Ring Opening

DOI: 10.1021/jo00292a001

Source and publish data:

Journal of Organic Chemistry p. 1409 - 1410 (1990)

Update date:2022-08-11

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Authors:

Ryu, Ilhyong

Hirai, Akira

Suzuki, Haruhisa

Sonoda, Noboru

Murai, Shinji

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Article abstract of DOI:10.1021/jo00292a001

The reactions of (silylmethyl)cyclopropanes with haloboranes, such as BBr3 and BHBr2, result in desilylative ring opening to give homoallylboranes and boracyclopentanes, respectively.Coupled with subsequent oxidation procedure, these reactions provide ready access to homoallylic alcohols and 1,4-diols.

Full text of DOI:10.1021/jo00292a001

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