Fragmentation-Rearrangement of 2-Acyloxyalkylphosphonates - a Novel Route to Alkyl Metaphosphate Extrusion

DOI: 10.1039/C39920001003

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1003 - 1004 (1992)

Update date:2022-08-17

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Authors:

Jongh, Connie P. de

Modro, Tomasz A.

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Article abstract of DOI:10.1039/C39920001003

Thermolysis of dialkyl 2-acyloxyalkylphosphonates, resulting in the fragmentation to an alkene, ester and alkyl metaphosphate, represents the first example of a reaction in which alkyl group migration has to occur before the metaphosphate species can be extruded from the system.

Full text of DOI:10.1039/C39920001003

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