Nucleophilic replacement of hydrogen in para-substituted nitrobenzenes by phenylacetonitrile carbanion

DOI: 10.1023/A:1015315127634

Source and publish data:

Russian Journal of Organic Chemistry p. 100 - 103 (2002)

Update date:2022-08-10

Topics:

Authors:

Orlov Orlov

Sokovikov

Kotov Kotov

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Article abstract of DOI:10.1023/A:1015315127634

The kinetic relations holding in nucleophilic replacement of hydrogen in para-substituted nitrobenzenes by phenylacetonitrile carbanion suggest a complex reaction mechanism involving two alternative pathways. The direction of the process is determined by the structure of intermediate σ-complex.

Full text of DOI:10.1023/A:1015315127634

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