Niobium-catalyzed reduction of monofluoroarenes with LiAlH4

DOI: 10.1055/s-2004-822919

Source and publish data:

Synlett p. 1282 - 1284 (2004)

Update date:2022-08-11

Topics:

Authors:

Fuchibe, Kohei

Akiyama, Takahiko

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Article abstract of DOI:10.1055/s-2004-822919

It was found that monofluoroarenes were reduced to the corresponding hydrodefluorinated arenes by the treatment of 5 mol% of NbCl₅ and LiAlH₄. Based on the substituent effect observed, an aromatic nucleophilic substitution mechanism

Full text of DOI:10.1055/s-2004-822919

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