THE MECHANISM OF N-ALKYLATION OF WEAK N-H-ACIDS BY PHASE TRANSFER CATALYSIS

DOI: 10.1016/S0040-4039(01)80801-7

Source and publish data:

Tetrahedron Letters p. 297 - 300 (1985)

Update date:2022-08-11

Topics:

Authors:

Dehmlow, Eckehard V.

Thieser, Rainer

Zahalka, Hayder Ali

Sasson, Yoel

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Article abstract of DOI:10.1016/S0040-4039(01)80801-7

The alkylation of aromatic amines in the presence of inorganic bases is accelerated by a PT catalyst even if KHCO3 is the base.ArNR(1-) ions seem not to be involved.A novel type of mechanism for a PTC process is proposed.

Full text of DOI:10.1016/S0040-4039(01)80801-7

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