Tetrahedron Letters p. 7615 - 7618 (1998)
Update date:2022-08-28
Topics:
Simoni, Daniele
Invidiata, Francesco Paolo
Manferdini, Monica
Lampronti, Ilaria
Rondanin, Riccardo
Roberti, Marinella
Pollini, Gian Piero
Tetramethylguanidine-catalyzed addition of dialkyl phosphites to α,β- unsaturated carbonyl compounds, alkenenitriles, aldehydes and ketones constitutes a practical route to a variety of phosphonate synthons. The very mild conditions employed, together with the short reaction times, make the procedure highly versatile and tolerant to a range of functionalities. The proposed methodology is also convenient for the preparation of α- aminophosphonates.
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