Tetrahedron Letters p. 929 - 932 (1986)
Update date:2022-08-16
Topics:
Hirao, Toshikazu
Misu, Daisuke
Yao, Koichi
Agawa, Toshio
Organovanadium compounds generated in dichloromethane from equimolar amounts of vanadium trichloride and Grignard reagents underwent the chemoselective cross-coupling reaction with acid chlorides leading to the corresponding ketones.Treatment with allyl halides resulted in allylation of organovanadium compounds.In the case of propargyl bromide, regioselective displacement occured to produce allene derivatives.
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