SYNTHETIC MODELS FOR THE TRANSITION METAL BINDING SITE OF BLEOMYCIN. REMARKABLE IMPROVEMENT OF DIOXYGEN ACTIVATING CAPABILITY

DOI: 10.1016/S0040-4020(88)90017-8

Source and publish data:

Tetrahedron p. 2811 - 2820 (1988)

Update date:2022-08-30

Topics:

Authors:

Kittaka, Atsushi

Sugano, Yuichi

Otsuka, Masami

Ohno, Masaji

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Article abstract of DOI:10.1016/S0040-4020(88)90017-8

Model compounds for the metal binding site of bleomycin with a CH2CONH2 group (PYML-3) or a tert-butyl group (PYML-4) as steric environmental factors are synthesized.These exhibit metal binding properties similar to those of bleomycin.In particular, PYML-

Full text of DOI:10.1016/S0040-4020(88)90017-8

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