Journal of the American Chemical Society p. 7786 - 7788 (1986)
Update date:2022-08-11
Topics:
Leyva, Elisa
Barcus, Robert L.
Platz, Matthew S.
Photolysis of diphenyldiazomethane (DPDM) in frozen alcoholic matrices gives ground-state triplet diphenylcarbene (DPC).At 77 K 3DPC reacts primarily with alcohols by OH insertion to give ethers.Photolysis of 3DPC produces an excited carbene 3DPC* which reacts with the matrix by H-atom abstraction to ultimately give alcohol-type products.Secondary photolysis of triplet fluorenylidene at 77 K is not as prevalent as that of 3DPC.
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