The first complete dechlorination of 1,1,1-trichloro-2,2-bis(4- chlorophenyl) ethane (P,P'-DDT) using metal-promoted alkoxyborohydride in a protic solvent

Article abstract of DOI:10.1080/00397910008087291

The reaction in situ of sodium borohydride with 2-methoxyethanol in 2- propanol in the presence of catalytic amount of NiCl₂ · 6H₂O generates a powerful dechlorinating system which dechlorinates 1,1,1-trichloro-2,2-bis (4-chlorophenyl)-ethane (DDT) to 1,1-diphenylmethoxymethane(80%) and 1-(p- chlorophenyl)-1-phenylethane(10%) in 6 hours at 82-84 °C.

Full text of DOI:10.1080/00397910008087291

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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The First Complete
Dechlorination of 1,1,1-
Trichloro-2,2-Bis(4-
Chlorophenyl) Ethane (P,P'-
DDT) Using Metal-Promoted
Alkoxyborohydride in a Protic
Solvent
a
Seyed-Mohammad H. Tabaei , Elaheh Satarinezhad
a
a
a
a
,
Seyed-Hassan Seradj & Gholam-Reza Ebrahimian
Department of Medicinal Chemistry, School of
Pharmacy , Shiraz University of Medical Sciences ,
Shiraz, 71345--1583, Iran
Published online: 04 Dec 2007.
To cite this article: Seyed-Mohammad H. Tabaei , Elaheh Satarinezhad , Seyed-
Hassan Seradj & Gholam-Reza Ebrahimian (2000) The First Complete Dechlorination
of 1,1,1-Trichloro-2,2-Bis(4-Chlorophenyl) Ethane (P,P'-DDT) Using Metal-Promoted
Alkoxyborohydride in a Protic Solvent, Synthetic Communications: An International
Journal for Rapid Communication of Synthetic Organic Chemistry, 30:1, 43-51, DOI:
10.1080/00397910008087291
To link to this article: http://dx.doi.org/10.1080/00397910008087291

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