Tetrahedron p. 15991 - 16008 (1997)
Update date:2022-08-17
Topics:
Zamir, Lolita O.
Balachandran, Sarala
Zheng, Yi Feng
Nedea, Maria E.
Caron, Gaetan
Nikolakakis, Anastasia
Vishwakarma, Ram A.
Sauriol, Francoise
Mamer, Orval
A detailed investigation of the rearrangement of the major taxane from Taxus canadensis enables to suggest the sequence of the reactions involved: 9-dihydro-13-acetylbaccatin III - abeo-taxanes with intact oxetane and acyl migration - abeo-taxanes with intact oxetane and deacylation - abeo-taxanes with opening of the oxetane and various acyl migrations including two unusual benzoyl shifts.
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