The synthesis of heteronuclear transition metal clusters derived from alkylidyne tricobalt cluster precursors. I. The reaction of (μ3-CCl)Co3(CO)9 with transition metal carbonyl anions. The crystal and molecular structure of (μ3-CCl)

Article abstract of DOI:10.1016/0022-328X(93)80364-H

Metal exchange reactions were used to produce heterometallic clusters derived from alkylidyne tricobalt precursors. Reaction of the cluster (μ₃-CCl)Co3(CO)9 with the potassium salt of (η⁵-C5H5)Mo(CO)3^- produced (μ₃