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DOI: 10.1039/C5CY00919G
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1–Nitro Propene: 1 HNMR (300MHz, CDCl3): δ 2.12 (d, 3H, CH3, 14. V. Ramamurthy.; P. H. Lakshminarasimhan.;G. P. Grey.;L. J.
Johnston, Chem.Com. 1988 , 2411
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J = 6.9 Hz), 7.00 (d, 1H, Ha, J=16.5Hz,), 7 .18 (m 1H, Hb) m/z = 87.
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Tableꢀ3: Decarboxylative nitration of α, βꢀ Unsaturated Acids by using Zeolite Y in Acetonitrile medium
S.N
Substrate
Isolated Products
Conventional
Sonication
Microwave
R. T Yield
R. T
(hr)
5
Yield
(%)
72
R. T
Yield
(%)
75
(min)
60
(sec)
90
(%)
78
1
CA
βꢀ Nitrostyrene
2
3
4
5
6
7
8
9
10
2ꢀCl CA
4ꢀCl CA
4ꢀOH CA
4ꢀNO2 CA
4ꢀOMe CA
AA
CRA
2ꢀMe CA
4ꢀMe CA
2ꢀCl βꢀ Nitrostyrene
4ꢀ Cl βꢀ Nitrostyrene
4ꢀ OH βꢀ Nitrostyrene
4ꢀ NO2 βꢀ Nitrostyrene
4ꢀOMe βꢀ Nitrostyrene
1ꢀ Nitro ethene
1ꢀ Nitro propene
2ꢀ Me βꢀ Nitrostyrene
4ꢀMe βꢀ Nitrostyrene
5.5
5
4
6
4
5.5
6
6
68
72
80
70
75
62
65
66
74
80
70
50
90
50
100
90
85
75
70
70
85
74
76
65
66
65
76
120
100
80
200
100
180
150
180
90
70
75
88
75
75
66
70
70
80
4.5
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