REXTION OF SUPEROXO Co(III) COMPLEX WITH QUINONES FORMATION OF A SEMIQUINONE Co(III) COMPLEX

DOI: 10.1016/0040-4039(80)80157-2

Source and publish data:

Tetrahedron Letters p. 4853 - 4854 (1980)

Update date:2022-08-11

Topics:

Authors:

Nishinaga, A.

Tomita, H.

Matsuura, T.

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Article abstract of DOI:10.1016/0040-4039(80)80157-2

The superoxo complex (3-) was found to act as a reducing agent towards quinones.One-electron reduction took place with o-quinone whereas two-electrons reduction with p-quinones. 3,5-Di-t-butyl-o-benzoquinone gave the corresponding semiquinone Co(III) complex quantitatively.

Full text of DOI:10.1016/0040-4039(80)80157-2

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