Chemistry Letters p. 769 - 772 (1992)
Update date:2022-08-17
Topics:
Akazome, Motohiro
Kondo, Teruyuki
Watanabe, Yoshihisa
Indole derivatives were readily prepared from the reductive N-heterocyclization of o-nitrostyrene derivatives in the presence of a catalytic amount of PdCl2(PPh3)2 - SnCl2 under carbon monoxide pressure (20 kg/cm2) at 100 deg C for 16 h.With o-nitrostilbene, 2-phenylindole was obtained in 75percent yield.
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