Asymmetric Hydrosilylation of Symmetrical Diketones Catalyzed by a Rhodium Complex with Trans-Chelating Chiral Diphosphine EtTRAP

DOI: 10.1016/00404-0399(50)0981H-

Source and publish data:

Tetrahedron Letters p. 5239 - 5242 (1995)

Update date:2022-08-28

Topics:

Authors:

Kuwano, Ryoichi

Sawamura, Masaya

Shirai, Junya

Takahashi, Masatoshi

Ito, Yoshihiko

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Article abstract of DOI:10.1016/00404-0399(50)0981H-

Asymmetric hydrosilylation of symmetrical diketones with diphenylsilane in the presence of catalytic amount (/ = 100> of rhodium complex coordinated with trans-chelating chiral phosphine ligand EtTRAP gave corresponding optically active symmetrical diols with high enantiomeric excesses.

Full text of DOI:10.1016/00404-0399(50)0981H-

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