Hydroesterification of Olefins Catalyzed by Pd(OAc)2 Immobilized on Montmorillonite

DOI: 10.1021/jo00106a042

Source and publish data:

Journal of Organic Chemistry p. 250 - 252 (1995)

Update date:2022-08-11

Topics:

Authors:

Lee, Chul Woo

Alper, Howard

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Article abstract of DOI:10.1021/jo00106a042

Palladium acetate immobilized on montmorillonite is an efficient catalyst for the hydroesterification of olefins with carbon monoxide and methanol, in the presence of triphenylphosphine and an acid promoter, affording branched chain esters.The reaction is regiospecific for aryl olefins as well as for vinyl benzoate and regioselective for aliphatic olefins.

Full text of DOI:10.1021/jo00106a042

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