Tetrahedron Letters p. 809 - 812 (1993)
Update date:2022-08-16
Topics:
Fry, Albert J.
Sirisoma, U. Nilantha
Lee, Agnes S.
Benzal chloride is converted to a mixture consisting primarily of cis- and trans-stilbene by the action of electrochemically-generated cobalt(I)(salen). The process involves a sequence involving electrocatalytic conversion of benzal chloride to a mixture of meso- and dl -1,2-dichloro-1,2-diphenylethane, followed by electrocatalyzed conversion of the latter to the stilbenes. Each of the diastereomeric dichlorides affords the same mixture of stilbenes under the reaction conditions.
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