Journal of Physical Chemistry p. 4544 - 4548 (1987)
Update date:2022-08-11
Topics:
Turro, N. J.
Zimmt, M. B.
Lei, X. G.
Gould, I. R.
Nitsche, K. S.
Cha, Y.
The effects of additives on the recombination efficiency and exit rates of micellized benzyl radicals have been studied by steady-state CIDNP, steady-state product analysis, and time-resolved optical absorption techniques.The results indicate that the efficiency of triplet geminate pair recombination increases monotonically as the micellar volume increases.Aggregation numbers of SDS micelles were deduced as a function of additive concentration from CIDNP measurements and were found to be consistent with literature values.
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