Journal of Organometallic Chemistry p. C35 - C38 (1985)
Update date:2022-08-11
Topics:
Demerseman, Bernard
Coupanec, Pascale Le
Dixneuf, Pierre H.
Electron-rich alkynetitanium(II) complexes Cp2Ti(PhCCPh)(PMe3), (MeCp)2Ti(PhCCPh)(PMe3) and Cp(C5Me5)Ti(PhCCPh) react with molecular hydrogen and are catalyst precursors for the hydrogenation of alkynes.Selective hydrogenation leading to cis-olefins takes place in the presence of an excess of PMe3 under mild conditions (1 atm H2).
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