Tetrahedron Letters p. 8791 - 8794 (1998)
Update date:2022-08-11
Topics:
Ramachandran, P. Veeraraghavan
Reddy, M. Venkat Ram
Rudd, Michael T.
De Alaniz, Javier Read
Ethyl acrylate and acrylonitrile fail to undergo efficient Baylis- Hillman reaction with fluoral, but provide good yields of products with pentafluorobenzaldehyde. Alternately, unsubstituted and β-substituted [α- (ethoxycarbonyl)vinyl]aluminum react with perfluoroalkyl and -aryl aldehydes and ketones to provide the α-hydroxyalkenylated fluoro-organic compounds in good to excellent yields.
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