Chemistry Letters p. 871 - 874 (1986)
Update date:2022-08-16
Topics:
Miyasaka, Tadayo
Ishizu, Hidehiro
Sawada, Akihiro
Fujimoto, Akiko
Noguchi, Shunsaku
(E)-Phenyl 2-pyridyl ketone O-acyloximes (PPAO) could be highly activated by metal ions such as Fe(3+), Cu(2+), and Zn(2+), and the most effective catalyst for the synthesis of carboxylic esters was found to be Zn(2+).Furthermore, sterically hindered carboxylic esters were easily obtained utilizing PPAOs and alcoholates in high yields.
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