Catalytic esterification of alcohols, carboxylic acids and transesterification reactions with cerium(IV) triflate

DOI: 10.1246/bcsj.72.455

Source and publish data:

Bulletin of the Chemical Society of Japan p. 455 - 458 (1999)

Update date:2022-08-16

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Authors:

Iranpoor, Nasser

Shekarriz, Marzieh

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Article abstract of DOI:10.1246/bcsj.72.455

Esterification reactions of alcohols with acetic, chloroacetic, trifluoroacetic, propionic, stearic, and benzoic acids were catalyzed with Ce(OTf)₄ in a solvent or under solvent-free conditions with high yields. The formylation and acetylation of primary and secondary alcohols were also easily achieved in ethyl formate and ethyl acetate. A high retention of the configuration was observed in the acetylation and formylation of (-)-menthol.

Full text of DOI:10.1246/bcsj.72.455

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