Catalytic esterification of alcohols, carboxylic acids and transesterification reactions with cerium(IV) triflate

DOI: 10.1246/bcsj.72.455

Source and publish data:

Bulletin of the Chemical Society of Japan p. 455 - 458 (1999)

Update date:2022-08-16

Topics:

Authors:

Iranpoor, Nasser

Shekarriz, Marzieh

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.72.455

Esterification reactions of alcohols with acetic, chloroacetic, trifluoroacetic, propionic, stearic, and benzoic acids were catalyzed with Ce(OTf)₄ in a solvent or under solvent-free conditions with high yields. The formylation and acetylation of primary and secondary alcohols were also easily achieved in ethyl formate and ethyl acetate. A high retention of the configuration was observed in the acetylation and formylation of (-)-menthol.

Full text of DOI:10.1246/bcsj.72.455

Products guided by the article

Product name:Phenethyl acetate

Cas No:103-45-7

R&D Labs maybe for 103-45-7

Hangzhou Chemfar Ltd.

Contact:+86-571-87859231, 87859237, 87859239

Address:1606,Huarong Times Mansion, No.3880 Jiangnan Avenue, Binjiang District, Hangzhou, China, 310053
Xi'an Unique Electronic and Chemical Co., Ltd.

Contact:+86-029-88238008

Address:1703# B BUILDING WEST ELECTRONIC ZONE, XI'AN, CHINA
ANHUI CHEM-BRIGHT BIOENGINEERING CO.,LTD

Contact:86-561-4080321

Address:No.8 Lieshan Industrial Zone of Huaibei
Zhonghao (dalian) Research and Design Institute of Chemical Industry Co., Ltd

Contact:+86 411 84674606

Address:201, Huangpu Road , Shahekou District, Dalian ,116023-China
Wuhan Chemchemical Co., Ltd.(expird)

Contact:15973022782

Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.

Relevant to this article

Construction of Hierarchical Hollow Co9S8/ZnIn2S4 Tubular Heterostructures for Highly Efficient Solar Energy Conversion and Environmental Remediation

Doi:10.1002/anie.202000503
(2020)
Preparation and Absolute Configuration of (-)-(E)-α-trans-Bergamotenone

Doi:10.1002/hlca.19980810114
(1998)
Radiolytic yield of U^IV oxidation into U^V1: A new mechanism for U^v reactivity in acidic solution

Doi:10.1021/jp9051177
(2010)
Hydrogen peroxide induced activation of gene expression in mammalian cells using boronate estrone derivatives

Doi:10.1002/anie.201203222
(2012)
A facile regio- and stereocontrolled synthesis of (Z)-1,3- enylnylstannanes via cross coupling of (E)-α-iodovinylstannanes with terminal alkynes

Doi:10.1080/00397919908085971
(1999)
Paramagnetic semiconductors: Hybrid molecular materials based on ethyl- and methyl-pyridinium-substituted verdazyl radical cations and the Ni(dmit) ₂ anion (dmit = 1,3-dithiol-2-thione-4,5-dithiolate)

Doi:10.1246/bcsj.78.2114
(2005)

Article Doi