Tetrahedron p. 10977 - 10986 (1993)
Update date:2022-08-10
Topics:
Tomic, Srdanka
Ljevakovic, Durjica
Tomasic, Jelka
Deacylations of fully acylated D-glucopyranoses, methyl D-glucopyranosides, 2-acetamido-2-deoxy-D-glucopyranoses glucopyranoses and methyl 2-acetamido-2-deoxy-D-glucopyranosides catalyzed by rabbit serum or the esterase isolated from rabbit serum were investigated. Depending on the structure of the acyl protecting group a high degree of regioselectivity is observed. Products of enzymic hydrolysis followed by intramolecular migrations of acetyl groups are also described.
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