A MIMIC STUDY ON COENZYME-B12 USING ORGANOCOBALOXIMES. THE REARRANGEMENT OF 1-SUBSTITUTED-2-OXOCYCLOPENTYLMETHYL RADICAL

DOI: 10.1246/cl.1981.33

Source and publish data:

Chemistry Letters p. 33 - 36 (1981)

Update date:2022-08-10

Topics:

Authors:

Tada, Masaru

Miura, Kyo

Okabe, Masami

Seki, Shigetaka

Mizukami, Hideyuki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/cl.1981.33

The radical cleavage of the carbon-cobalt bond of 1-phenyl-2-oxocyclopentylmethyl cobaloxime (1) and 1-ethoxycarbonyl-2-oxocyclopentylmethyl cobaloxime (2) gave only 3-phenylcyclohex-2-enone (7) and 3-ethoxycarbonylcyclohex-2-enone (8), respectively, by acyl migration.This rearrangement may be a reasonable mimicry of the ester migration mediated by coenzyme-B₁₂.

Full text of DOI:10.1246/cl.1981.33

Products guided by the article

Product name:3-phenylcyclohex-2-en-1-one

Cas No:10345-87-6

R&D Labs maybe for 10345-87-6

Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Shandong Ailitong New Material Co.,Ltd

Contact:+86-536-3226266

Address:zhongjia village, putong town , qingzhou city,Shandong Province,China
CHANGYI CITY FENGRUN FINE CHEMICAL CO.,LTD

website:http://www.fengrunhuagong.com

Contact:+86-536-7869976

Address:Changyi Coastal Economic Development Zone
Qingdao Kylin Trading Co., Ltd.

Contact:0086-532-68979884/58972912/68972263/65/88171519

Address:Room 2308,A building International Trade Center No.230 Changjiang Middle Road of Qingdao Economic Development Zone,Shandong,China.
Beijing Apis Biotechnology Co., Ltd.

Contact:86-010-67856775-8551

Address:NO.4PUHUANGYU ROAD,FENTAI DISTRICT, BEIJING, CHINA

Relevant to this article

Single photon ionization of methyl isocyanide and the subsequent unimolecular decomposition of its cation: Experiment and theory

Doi:10.1039/c9cp04310a
(2019)
C₁₅H₁₀ and C₁₅H₁₂ Thermal Chemistry: Phenanthrylcarbene Isomers and Phenylindenes by Falling Solid Flash Vacuum Pyrolysis of Tetrazoles

Doi:10.1021/acs.joc.5b01007
(2015)
Study on the "tin-ene" reaction of α-bromoacetophenone and metallic tin with aldehydes

Doi:10.1080/00397919608086752
(1996)
STEREOSELECTIVE ADDITION OF LITHIOETHYLACETATE TO BOC-L-PROLINAL. A CONVENIENT CHIRAL SYNTHETIC BUILDING BLOCK FOR THE PYRROLIZIDINE ALKALOID RING SYSTEM

Doi:10.1016/S0040-4039(00)84853-4
(1986)
4-Aza-N-benzyl bicyclo[2,2,2]octyl ammonium borohydride a highly chemoselective reagent for the reduction of aldehydes in the presence of ketones

Doi:10.1080/00397919208019248
(1992)
Synthesis and catalytic properties of neutral and cationic rhodium- And iridium-containing carbosilane dendrimers

Doi:10.1039/b211960a
(2003)

Article Doi