Directed Asymmetric Reduction of a Carbonyl Group via a New Homochiral Boronate Ester

DOI: 10.1016/S0040-4039(00)61477-6

Source and publish data:

Tetrahedron Letters p. 8155 - 8156 (1993)

Update date:2022-08-11

Topics:

Authors:

Mears, Richard J.

Whiting, Andrew

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Article abstract of DOI:10.1016/S0040-4039(00)61477-6

Homochiral β-boronate carbonyl derivative 4 directs the asymmetric reduction of the ketone moiety, providing 89percent enantiomeric excess of the (S)-diol 6, using borane-tetrahydrofuran as the reducing agent.

Full text of DOI:10.1016/S0040-4039(00)61477-6

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