Asymmetric catalysis. Asymmetric catalytic intramolecular hydrosilation and hydroacylation

DOI: 10.1016/S0040-4020(01)89370-4

Source and publish data:

Tetrahedron p. 4335 - 4346 (1994)

Update date:2022-08-11

Topics:

Authors:

Barnhart, Richard W.

Wang, Xianqi

Noheda, Pedro

Bergens, Steven H.

Whelan, John

Bosnich Bosnich

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Article abstract of DOI:10.1016/S0040-4020(01)89370-4

Catalysts of the type [Rh(chiral diphosphine)]⁺ efficiently catalyse the intramolecular hydrosilation of silyl ethers derived from allylic alcohols. The products can be converted to chiral 1,3-diols. High enantiomeric excesses (ee's) are observ

Full text of DOI:10.1016/S0040-4020(01)89370-4

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